[TheOtherHobbes]

You'd be floating in a haze of CO2 and sulphuric acid garnished with hydrogen sulphide, battered by raging convective winds which would make it very hard indeed to stay at a fixed altitude - which means the outer temperature would fluctuate by 10C to 50C or so without massively powerful altitude control.

You can't just drift there as if you're in a hot air balloon eating sandwiches and enjoying the view.

Venus might not be completely impossible, but it's still one of the less hospitable destinations in the solar system.

Also, smelly because of the H2S.

[azernik]

On the other hand, Mars requires you to live in a radiation-shielded pressure vessel.

I think the real killer is that it's hard to build and maintain infrastructure when floating on balloons - much easier to run a spaceport on Mars, or to get to all the useful surface resource deposits. On Venus you'd have to build literal castles in the air, using only only what you can pull out of the atmosphere or ship in from orbit.

Not to mention Mars is at the bottom of a much shallower gravity well.