Python 2.4.2 for DOS/DPMI, built on the DJGPP platform, is also available”.
So, yes, there was one. The link (http://www.caddit.net/pythond) works, and seems to still have the binary. You will need a ”proper Long Filename Driver for your platform” to fully enjoy it.
I learned Python 1.4 on DOS (with DJGPP). I think there were binary releases, but you couldn't use them if you needed any third-party C modules. There was no dynamic linking on DOS so you needed to statically link any C code you were using into python.exe. This was a huge pain but it also taught me a ton about both C and Python.