In Go, chaining is not idiomatic. For one, it becomes more challenging to determine where the error occurred if you want to try to handle the error instead of failing. Also, it requires each function in the chain to detect if an error has already occurred.
Clearly a fluid API can not return a 2+ tuple as its results so the error issue you note is a non-issue.
The clean way to deal with errors in fluid APIs is to have a terminal .init() that returns an error (which can also specifically note which options are "illegal", etc.)
IMO, keep it simple and remove the optional features if possible is also a good choice. If my golang API is complex, then I might aswell have done it in C++ :)
Interfaces are generally a better solution.