| I've recently had to become pretty familiar with this subject for work, and your comment is only partially correct. Li-Ion battery degradation is generally modeled as two (roughly additive) components, called calendar and cycle aging. Calendar aging is what you're talking about in your comment - it's basically determined by the temperature and state of charge. Both of these impact the rate of chemical processes that lead to loss of lithium and active material. This is what happens when the battery is sitting on the shelf. Cycle aging, on the other hand, happens when you charge or discharge the battery and is driven mostly by the actual volume change in the anode and cathode when they get lithiated (it's quite significant, up to 15% or so in some materials). This introduces mechanical stress, which can break the protective film that forms between the electrodes and electrolyte and allow chemical degradation to proceed at a faster rate. The degree of mechanical stress is mostly determined by the depth of discharge, although rate of charge and discharge is also believed to be important. Cycle degradation is also impacted by the temperature at which the battery is cycled, in a similar way to calendar aging. With high temperature variance (low temperatures will wreck your batteries too, and I can't recommend keeping them at 5C), calendar aging is the dominant mode. This is absolutely the case with cell phone batteries. However, electric vehicles, especially higher end ones like the Tesla, have an active cooling system that keeps the battery at a constant temperature, even when the car is "off". This is why many EVB warranties will be voided if you let them run out of charge for more than 14 days - at that point, the cooling system isn't working and your poor battery is at the mercy of the elements. Under closely controlled temperatures, cycle aging is the most important factor, and it's dominated by depth of discharge. If you drain the battery as far as it will allow you every day, it's going to be hosed. If you only go down to about 80% of the allowed charge every other day, it'll last for quite a while. These numbers are roughly correlated, obviously, with the mileage on the car, but the relationship is not simple, and I'd caution against considering mileage to be a good determinant of battery degradation. Some good sources if you want to learn more: A fairly simple model of degradation (ignores charge/discharge rate):
https://www.researchgate.net/publication/303890624_Modeling_... A thesis on the subject, goes into great detail and has an excellent bibliography:
http://webfiles.portal.chalmers.se/et/Lic/JensGroot.pdf |