[URSpider94]

While you are right that this is the statistical definition of entropy, there are two issues: first, entropy is a unitless quantity, so defining it exactly doesn't actually move the ball forward in terms of defining units of measure. Second, outside of its theoretical underpinnings, physicists and chemists hardly ever talk about absolute values of entropy, they almost always use differences in entropy -- which factors out the need to define the exact number of microstates present before and after.

[amluto]

> first, entropy is a unitless quantity

The parent post asked about defining temperature in terms of more fundamental units. Entropy is typically written in J/K. If you treat it as dimensionless, then you get a definition of temperature in terms of energy for free. My point is that you can, in principle, actually do an experiment to make this useful.