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by philipkglass 3431 days ago
I love James Sheridan Muspratt's Chemistry, theoretical, practical, and analytical, as applied and relating to the arts and manufactures from 1860.

Volume 1: https://archive.org/details/chemistrytheoret01muspuoft

Volume 2: https://archive.org/details/ldpd_10922488_002

Most of the theory is nonsense by modern standards. But it's amazing to see how sophisticated the chemical process industries were already in the mid 19th century. And it's self contained: the manufacturing processes start from plant matter, things you can dig out of the earth, or other materials whose manufacture is described in the same book. The difference between this and a modern chemistry or chemical engineering textbook is, for a rough analogy, the difference between exploring how computers work on an Apple II vs. on a powerful modern laptop with all the Debian packages installed. The modern environment is broader and more powerful, but the older one has the benefit of making all the pieces visible at once and down to a low level. (Well, it's a benefit for the curious anyway. I won't claim that experience with old 8 bit computers makes for measurably better developers, or that reading dusty historical tomes makes for more capable chemists or ChemEs.)

Another thing that I enjoy about old chemistry books is the engagement of all the senses. Chemists observed and wrote about color, crystal texture, scent, the sounds procedures made, and even taste. Bad for life expectancy, great for reading. NMR spectra, though far less ambiguous and far safer for identifying substances, just aren't as much fun to read. The procedures that are described may be horrendously unsafe but they also reliably include enough details to reproduce. I hate the abbreviated style that you see in some modern articles where the authors are thrifty with detail in the experimental section. These old works were written to inform other people of useful and/or striking observations about nature, not to grind for XP on the track to tenure, and it shows.

1 comments

Yes, A NOESY would be boring compared to the aesthetics! Long live Varian, Bruker, and Oxford mags!