Nope. Just rerouted packets going for 8.8.8.8 somewhere else; that's a MITM, not a compromise (although with an unauthenticated service such as DNS, the difference is academic for the client). Still, the sites are still accessible if you can get the IP address from somewhere else - which can be a different DNS server or even the hosts file.
I do agree that such block is enough to deter most non-technical users.
I do agree that such block is enough to deter most non-technical users.