Don't do that. You've essentially just turned the old hashes into plain-text passwords, and how sure are you that those hashes don't exist in backups anywhere?
No, not exactly. An adversary who has the old hash, but not the plaintext that it represents cannot login because scrypt(H(H(value))) != scrypt(H(value)). This is not considering the offline crackability of a compromised hash. But there are legitimate situations where upgrading the password backing to a modern slow hash is preferable to continuing to use the old hash or worse storing the old hash as a field for a long time so that when a breach happens both the new and old hashes are available.
There are user experience battles when talking about forcing a million users to change their passwords in a real system. Hashing the hash may be vastly preferable to management nixing the security upgrade. A password updating schema that changes the hash as users login and eventually locking the accounts of users who have not logged in for an extended period of time can accomplish rolling the hashes without having to tell users to change their passwords.
There are user experience battles when talking about forcing a million users to change their passwords in a real system. Hashing the hash may be vastly preferable to management nixing the security upgrade. A password updating schema that changes the hash as users login and eventually locking the accounts of users who have not logged in for an extended period of time can accomplish rolling the hashes without having to tell users to change their passwords.