Developer on Fire[1] tends to feature more personal interviews with software developers.
Software Engineering Daily[2] produces episodes at a similar rate to the previous podcast but discussion tends to be product-oriented.
Coder Radio[3] can be good fun sometimes. The hosts can sometimes be a bit over the top.
[0] http://www.se-radio.net/ [1] http://developeronfire.com/ [2] http://softwareengineeringdaily.com/ [3] http://www.jupiterbroadcasting.com/show/coderradio/