[floppydisk]

First off, relax. You want to be there, they want you to be there. You're already "in". Working relationships will begin to develop naturally in the first couple of months as you get comfortable with them and they get comfortable with you. You accelerate this process by asking questions when you don't know or understand something and get comfortable giving your opinion on things.

Friendships, depending on what you're going for, will naturally evolve with time. Go out to after work social activities (or organize a happy hour every so often), some of the same meet ups, and start building shared experiences with your coworkers. Over time, this will morph into deeper relationships.

Congrats on the new gig! Relax, have fun, and learn a ton!