Using that as a baseline (though it has changed over time) means the probability of having at least one foreign-born parent is 25%.
Of the remaining 75%, the probability that at least one of the grandparents is foreign born is 42%.
0.25 + 0.75 * 0.42 = 56% chance that someone in the US is a 1st or 2nd generation immigrant.
Sure enough, "60% of top 25 tech companies founded by 1st and 2nd generation immigrant" is almost exactly what's expected if a company is founded by a single person.
BTW, the table contains at least one error. It says that William Hewlett is not a first or second generation immigrant.
Out of the top 10, only Google (1 out 2 confounders) and Qualcom (1 of 7 cofounders) I'd count as companies that were built by real immigrants.
Incidentally both are Jews whose families left persecution in Europe (Italy and USSR).