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Low-Background Steel (en.wikipedia.org)
359 points by confeit 2164 days ago
19 comments

Low-background lead is also sought after in shipwrecks [0]. With lead it isn't contamination from nuclear tests that's the issue, but natural radioactivity that needs hundreds of years to decay.

[0] https://www.theatlantic.com/science/archive/2019/10/search-d...

It's always confused me how mined lead somehow has more radioactivity. Shouldn't the lead in the ground also have decayed over time?

Also, it makes me wonder why someone enterprising hasn't stockpiled a few tons of the stuff somewhere to let it become low background lead for the future. You'd think that some government or another would be able to drop a million dollars on putting a lead stockpile somewhere safe for the future.

> It's always confused me how mined lead somehow has more radioactivity. Shouldn't the lead in the ground also have decayed over time?

Looking into this a bit, it seems that the radiation in refined lead isn't coming from the lead ore, but from the other materials used in the smelting process. Old lead would have had time for all those things to decay.

I wonder why manufacturers don't just use filtered atmospheric air in the process to create low-background steel, if it is infact valuable.
Extremely difficult to separate different molecules that differ by only the weight of a single neutron.
They are using Oxygen, Oxygen can't become radioactive for longer than a few seconds anyway.

All they need to do is filter for pure oxygen, nitrogen is fine as well.

It's really just CO2 that's the problem.

Not valuable enough to bother.
So salvage it from sunken ships is cheaper then?
How do you suggest filtering by isotope?
As others said, simply separating the CO2 away would mostly get rid of the problem - all non-stable isotopes of Oxygen have a max half life of 122 seconds, but, for the record, isotopic separation is easy when there is a very large difference in atomic weight.

In Uranium's case it's difficult because it's 235/238 = 1.28% (actually way worse - Uranium hexafluoride is used, which adds 114 units, bringing the ratio down to 0.86%)

In Oxygen's case the ratio would be at least 6.6% (15 vs 16).

Most importantly in Uranium you are interested in the tiny amount of U235, while in Oxygen you'd be interested in the huge bulk of O16, O17, O18, which are the stable isotopes. O16 alone is 99.762% of all Oxygen, and you can afford to lose half in your centrifuge if it spares you a few cycles, it's not exactly hard to come by.

Just filter for oxygen. Radioactive oxygen doesn't last more than a few seconds.

The issue is contamination with Carbon (CO2). Nitrogen also is not a problem.

I mean, there are ways to do this. None of which are remotely cost effective.
Centrifuges
What would be the timeframe over which one would make a profit? Our global financial system is based on the 30 year U.S. Treasury bond. There are no economic incentives to plan beyond 30 years.
Probably a few hundred years, so yeah, it wouldn't be worth it to the people doing it at all within their lifetime. That's why I was suspecting a far-sighted government or such with enough money to squirrel it away for future use.

The US sorta has a few things like that already--the oil reserve & the stockpile of helium, though I understand the latter is winding down still. Given the importance of those materials to science, I would think that there might be some scientifically-motivated project to protect our access to such things.

This is interesting. Can you point me to anything that will expand on/help me understand this?
I don't know of any good sources. But my understanding is that there are very few "Methuselah bonds" by which it is meant instruments that have lifespans of 50 years or more. So anybody with a profit motive has no advantage for putting money into something that would have a longer term focus. This explains to me why, for example, banks are still loaning money for buildings on Miami Beach. I would love to understand the dynamics better. It seems to me that only governments can be planning for longer terms. China, maybe?
Dykes are cheap.
Forget filters. It would have to be done in a vacuum and you would need to centrifuge the required gasses/carbon. It is possible in small batches, but the sunken ships do exist ready to harvest. Maybe in the future the market will come.
And here https://physicsworld.com/a/ancient-romans-join-neutrino-hunt...

I had some low radiation lead for a while, makes for an interesting curio. As I recall its providence was re-melted musket balls from a shipwreck in the Bahamas.

nit: provenance
Yeah :-) I kept it as a neat hack for selling lead from a shipwreck that had paid for itself by selling off the gold and other bits, and the salvage operator was effectively eeking out a few more bucks from the geek crowd :-).
This comes up on HN every now and then, it is how I learned about low background steel. If this is new to you, you may also enjoy reading about the cesium content of wine: https://www.technologyreview.com/2018/07/19/141390/fukushima...
Is there a particular trigger for this post?

Is this a case of someone stumbling into the concept and wanting to share it with the world? Is there some trend in SV around low-background steel right now?

Genuinely curious about the phenomenon of posts around topics that have a great deal of understanding and aren’t necessarily trending in the general news cycle.

I saw it linked from the comments on a Tweet by Karpathy and found it intellectually curious.

> By posting GPT generated text we’re polluting the data for its future versions

https://twitter.com/karpathy/status/1284660899198820352

You seem to have gotten your replies mixed up. This looks like it's for the GPT "Bitcoin" thread?
No, low-background steel is mentioned in the replies. It's similar in the sense that GPT-3 generated text is going to contaminate the data we collect from now on.
Ah, yeah, that makes sense. My bad.
It could be as simple as OP being one of [today's lucky 10,000](https://xkcd.com/1053/).
OP answered in a sibling comment, but might additionally be interesting to know why a repost like this gets upvoted: I upvoted it because I didn't know of it (this is the first time I see it) and I wasn't aware that there is that much radiation lingering from tests decades ago, which was interesting to me.
There was a post a week or so ago where low-background steel was discussed in the comments. I can't find it on Google though. Probably someone saw that and either made a calendar reminder for a few days out to post it or had it in their open tab backlog.

Edit: I'm pretty sure it was the knife steel post.

Low background lead was recently mentioned on xkcd[0]. Maybe that circled back to HN?

[0] https://xkcd.com/2321/

There was a recent post on the trinity test

Someone going on a binge from that, through discovering how Kodak found out about nukes from film and low background steel isnt a huge stretch either

One of the latest xkcd comics mentioned low background steel. I assume that is the reason
The 75th anniversary of the first nuclear bomb test was just a few days ago, on July 16th. It's been in the news a bit lately, and this topic is related.
If I had to guess, the moderators curate certain technical discussions to the top.

But I’d wager that Reddit curates their front page too. There’s no way an organic algorithm is populating the front page.

I'm not sure about some of the the claims of the Wikipedia article.

* First, the article implies that air continues to be the main reason for contamination of steel. It might have been the case, back when atmospheric levels for radioactive elements were higher. However now there is less contamination in the air [0], and the main source for contamination is recycled steel. Either because it itself is non-low-background steel or because e.g. medical radioactive sources were put into the scrap metal supply. See also this IAEA report on scrap metal [1].

* The article also says that the primary source for low background steel are shipwrecks, but I think that's an exaggeration. Especially, the topic came up on hn a few weeks ago and someone in the know debunked it [2].

[0]: https://upload.wikimedia.org/wikipedia/commons/e/e2/Radiocar...

[1]: http://web.archive.org/web/20111016193221/http://www.iaea.or...

[2]: https://news.ycombinator.com/item?id=23666436

You should update the Wikipedia article. I mean, you've already got the references.
These isotopes are also used to help spot fake art

https://physicsworld.com/a/nuclear-fallout-used-to-spot-fake...

If I understand it right, it's possible to produce non-radioactive steel but doing do is just a lot more expensive for the time being than just getting it from old sources.
The scene of the battle of Midway would also hold a hoard of nice steel (the Japanese lost a lot of ships including aircraft carriers). I understand that Scapa Flow has been heavily salvaged with only 7 out of 52 ships still down there.
The Battle of Midway was fought in spectacularly deep water, on the order of 17,000-18,000 feet deep. This would make salvaging difficult, if not impossible. Scapa Flow is shallow enough for divers.

Once we run out of cheaply salvageable steel, we'll likely turn to steel smelting processes that do not introduce air into the steel. These processes require dramatically more energy and are thus more expensive, but will still be way less expensive than attempting to salvage at deep ocean depths.

> Once we run out of cheaply salvageable steel, we'll likely turn to steel smelting processes that do not introduce air into the steel.

This would be exceptionally difficult, as oxygen is a basic requirement for steel making as we have ever known it. Steel is made from iron mixed with carbon and then heated to melt. Then oxygen is added which burns the excess carbon into carbon dioxide and reacts with all of the other reactive contaminants and brings them to the surface where they can be cupped off as slag. The melt is poured and cooled and you have steel. Early steel processes used air, blast into the furnace with high powered pumps. Modern steel is made with purified oxygen from cryogenic processes (and there are even designs floating around for steel mills which use the turboexpander from the oxygen processing to help generate electricity to drive the mill).

Without oxygen, you'd have to start with very, very clean iron ore (containing nothing but iron and whatever you wanted to alloy with the final steel), and add exactly the right amount of carbon (which is also exceptionally difficult, since carbon is light and the heat will want to make it sublime anyway). Odds are such a steel would still contain so much impurity as to require a second melt in a vacuum arc furnace, which also would dramatically drive up the cost.

While there might be a future making steel like this in space, I'm not counting it as very likely in the slightest to happen in this century.

It's much easier to use exceptionally clean oxygen - the mill could use an oxygen generation process (like a hydrogen peroxide chemical process plant being added to the mill), or by ultrafiltration of the process oxygen (which seems more realistic all told).

Start with iron pentacarbonyl, which is conveniently a liquid that can be distilled. That gets rid of nearly all impurities.
Iron bottom sound would definitely be a better bet, although the fact that it's a grave site definitely gives pause. Scapa Flow is relatively unique in that it's a large collection of ships, without being a grave site, and being near the surface.
> steel smelting processes that do not introduce air into the steel.

Air is perfectly fine. Both Oxygen and Nitrogen do not stay radioactive for longer than a few seconds. It's CO2 that is the problem, specifically the carbon.

And of course any other random impurity.

They could just use cryogenicaly distilled air, and take the nitrogen-oxygen part (the boiling points are very close).

Yeah but there are issues with disturbing a grave site. A lot of people don't take kindly to that, especially when it's a military grave.

Scuttled ships, well in theory anyways, shouldn't have had anyone on board.

The grave site was in regards to Midway. 9 german sailors were killed while surrendering On land. None were killed on the the ships themselves.
How deep are the sunken ships at Midway?
Probably too close to the Pacific Proving Grounds.
Since tabacco gets its cancer making polonium from the air, I wonder if smoking got riskier because of the nuklear testing.
Do you have more information on this? Seems interesting!
Just search for the paper on the topic, written by the Phillip Morris Unbiased Research Group. it explains how frogs breathing air got more cancer then frogs trapped in airtight boxes and only allowed to breathe exhaled tobacco smoke, who mostly died for other reasons. seems legit...
Well there is much known fact about how tabacco absords radiating material. But until now I have not found anything about how that changed during the ages. But simple logic tells me there must have been an affect on how dangerous smoking is.
A few years ago it was in the news that several militairy shipwrecks vanished in indonesia waters[0], presumably plundered for the steel.

[0] https://www.bbc.com/news/world-asia-37997640

Can it be recycled without contamination of existing radiation in other elements used to melt it and such?

I mean how do they create the instruments in the first place and keep the radiation low?

Im always curious how we will send messages to future civilizations. How will we ensure we’ll be remembered or even noted in 10,000, 100,000, 1 million years? How can we prevent the same disaster(s) that eventually wipes our civilisation out from repeating again in future intelligent generations (human or otherwise)

Could environmental markers like these be the way? After all, it’s how we look at the past today

We already know what can last for literally millions of years: Life.

Maybe we could encode some information in birdsong, tree rings, or the matting patterns drawn by fish in the seafloor. :)

https://www.youtube.com/watch?v=hpdlQae5wP8

This reminds me of Whisper, one of my favorite exotic alien concepts. The alien civilization in question has selected a planet with as stable environment as possible, and planted it full of genetically engineered grass. The sound of wind blowing through the grass creates an acoustic computer which hosts a virtual space its creators have uploaded themselves into.

https://www.orionsarm.com/eg-article/470007b39d192

I have never heard anything like that (using sound) before. Amazing!
A SF short story about a biologically encoded message from ancient aliens (written by one of the Autodesk founders): We'll Return, After This Message by John Walker

https://www.fourmilab.ch/documents/sftriple/gpic.

It's fascinating that in 1983 it was thought that a 768-bit RSA number would take 40 million years to factor. (It actually took 26 - RSA-768 was factored in 2009.)
Or directly encode the message in DNA itself. I suppose the difficulty would be devising an encoding with enough redundancy or other features to preserve the information content over many generations of evolutionary pressures.
Our plastic is going to be around far longer than us. Left by itself plastic decays on geological timelines.[1]

1. http://worldwithoutus.com/excerpt.html

If by "stay" you mean spread microplatisc, that carries no information, then maybe. The jury is still out, but it looks like it'll last a long time.

But plastic is not a good candidate to hold messages for a long time. It degrades in a few years into some unusable stuff. Glass is a much better candidate.

Unless a microbe finds a way to use it as fuel
If you knew that a past civilization or even non-human intelligent species had been wiped out by war or climate change, would it change your actions?

I don't know there's much we could say that future civilizations would care to listen to.

It would certainly be big news.
Deep Time: How Humanity Communicates Across Millennia Paperback by Gregory Benford explores some of those questions. It comes into practical questions when trying to mark nuclear waste dumps.
The problem with that is, judging by our own behavior, an unknown ancient structure makes humans investigate it, try to dig it up, etc. Placing a marker isn't the problem, the hard part is communicating "nothing interesting, only death here, do not enter" in a way that someone in 10.000 years will heed the warning.
The solution is to build them everywhere and put the bad stuff in one of them. If you build enough then the chances of them excavating the one with nuclear waste is pretty low.
It occurred to me as they were taking down the cantilever (eastern) section of the Bay Bridge that lots of it would have been low-background, based on its construction in the 1930s.
That's how I first heard about this concept, which was fairly recently.
It's been pointed out it's wrong but, as a sometime nuclear spectroscopist, I'm curious: why are people insisting that β-decay, i.e. ¹⁴C, is the issue?
Can you make such steel by using clean air? Or it's not possible to purify it from radionuclides?
I seem to recall some of those shipwreckers getting nicked too?
no way to make steel without forced air?
Presumably no way that's cheaper than just getting it from shipwrecks. Doesn't seem like there's a huge demand, so old shipwrecks for the time being have enough supply.
What about using trapped air in shipwrecks, or glaciers.
War is stupid.
I need to find the source, but this has actually been a significant issue sourcing steel and titanium from China.