Most people should probably just use a third-party email service provider so they don't have to worry about issues like this. Deliverability is a pain to manage if you don't have to.
I didn't know about the existence of Google Postmaster Tools[0] so that was a cool discovery :)
Most cloud providers (e.g. Google [1] and Amazon) as well as ISPs block outgoing traffic on TCP port 25 (SMTP) so it's actually fairly hard to run your own SMTP server to begin with.